CHEM 125 · Workshop 1 · Life Chemistry Lab

The Railroad Track Method

One rule runs every calculation in Workshop 1: the unit you're converting to goes on top, the unit you're converting from goes on the bottom. The "from" cancels — done.

cm → inlb → gmL → Lcm³ → mm³g → molmol → atoms
The whole idea, in one line — convert 14.5 cm to inches
14.5 cm× 1.00 in2.54 cm =5.71 in
the "from" unit cancels the "to" unit survives answer
The one big idea

01 Units are just algebra

In algebra, when the same thing sits on the top and the bottom of a fraction, it cancels:

x · yx=y

Units do the exact same thing. If cm is on top and cm is on the bottom, they cancel — the same way an x cancels an x.

Your workshop says it directly: "one may treat the unit like an algebraic variable." That's the entire method. You're not memorizing formulas — you're stacking fractions so the unit you don't want cancels itself out, leaving the unit you do want.

The one rule

02 "To" on top, "from" on the bottom

Here is the whole method in one sentence. When you write a conversion factor as a fraction:

The unit you are converting TO goes on the top.
The unit you are converting FROM goes on the bottom.

Because your starting amount already carries the "from" unit on top, putting "from" on the bottom of the factor makes it cancel automatically — and the "to" unit is what's left standing. You never have to guess which way up the fraction goes.

Meters (m) CONVERTING FROM Centimeters (cm) CONVERTING TO 100 cm 1 m The unit you are converting to is on the top. The unit you are converting from is on the bottom.
Put it to work — convert 3.00 m to cm
3.00 m× 100 cmm =3.00 × 10² cm
STEP 1

Name your FROM and TO

What unit do you have (from)? What unit do you want (to)? Write the starting amount — it carries the "from" unit.

STEP 2

Build the factor

Write the conversion fraction with the to unit on top and the from unit on the bottom.

STEP 3

Cancel & solve

The "from" units cancel top-and-bottom. Multiply by the top number, divide by the bottom number.

⚡ Why you never guess "multiply or divide"

The rule decides for you. Put to on top and from on the bottom, and the setup is automatically correct. Multiplying by the top and dividing by the bottom just falls out of the fraction.

⚠ Watch out

If the unit didn't cancel, the factor went in upside down — you have from on top by mistake. Flip it so from sits on the bottom, underneath your starting amount.

Metric prefixes

03 The 1000-staircase

Your workshop's prefix table looks like seven things to memorize. It isn't — it's one staircase plus two in-between steps. Five of the seven prefixes sit exactly 1000 apart, in a row:

Mega M1.0 × 10⁶  ·  1.00 Mg = 1,000,000 g
▲ × 1000 ▼
kilo k1.0 × 10³  ·  1.00 kg = 1000 g
▲ × 1000 ▼
BASE gram · liter · meter10⁰ = 1
▲ × 1000 ▼
milli m1.0 × 10⁻³  ·  1000 mg = 1.0 g
▲ × 1000 ▼
micro mc1.0 × 10⁻⁶  ·  1,000,000 mcg = 1.0 g
▲ × 1000 ▼
nano n1.0 × 10⁻⁹  ·  1,000,000,000 ng = 1.0 g

Then just two extras squeeze between the base unit and milli — these are the only ones that break the 1000 pattern:

deci d1.0 × 10⁻¹  ·  10.0 dL = 1.0 L
centi c1.0 × 10⁻²  ·  100 cm = 1.0 m
Convert 0.653 L to mL  — "to" is mL, so mL goes on top
0.653 L× 1000 mLL =653 mL
✓ Sanity check

Milliliters are smaller pieces, so you need more of them → the number should get bigger. 0.653 → 653. ✔ If your answer shrank instead, you built the factor upside down.

Multi-step

04 Chaining & powered units

No single conversion factor? Add another fraction — one per step. Each one follows the same rule, so each unit cancels the next until only your target survives. Your workshop calls this doing it "serially."

Convert 4.53 kg to lbs  (1 kg = 1000 g · 454 g = 1.00 lb)
4.53 kg× 1000 gkg× 1.00 lb454 g =9.98 lb

kg cancels kg, then g cancels g. The only unit left standing is lb — proof the chain is built correctly.

⚡ Squared and cubed units

cm² means cm × cm, so the conversion happens twice. cm³ means cm × cm × cm, so it happens three times — and you square or cube the number too, not just the unit.

98.4 in² × (2.54 cm / 1.00 in)² = 98.4 × 6.4516 = 635 cm²

26.2 cm³ × (10 mm / 1 cm)³ = 26.2 × 1000 = 2.62 × 10⁴ mm³

Getting the answer right, not just close

05 Exact vs. measured factors

This is the part that costs points in Lab 1, and almost nobody teaches it. Not all conversion factors limit your significant figures. There are two kinds:

Which factors count toward sig figs?
Kind of factorExamplesEffect on sig figs
Exact — a definition, infinitely precise1 kg = 1000 g
100 cm = 1 m
1 cm³ = 1 mL
10 mm = 1 cm
None. Never limits your answer. Sig figs come only from the measured value.
Measured / rounded — a lab value someone determined454 g = 1.00 lb (3 sf)
29.5 mL = 1.00 fl oz (3 sf)
55.85 g/mol (4 sf)
6.02 × 10²³ (3 sf)
Yes. Counts like any other measurement — it can limit your answer.
✓ See the difference

2348 mL → L. The factor (1 L = 1000 mL) is exact, so it doesn't limit anything. 2348 has 4 sig figs, so the answer keeps 4: 2.348 L — not 2.35 L.

36.8 lb → g. Here the factor (454 g) is measured with 3 sig figs, and 36.8 also has 3, so the answer gets 3: 1.67 × 10⁴ g — not 16,707 g.

⚠ Write it so the sig figs are visible

985 in × 2.54 cm/in = 2501.9, which rounds to 3 sig figs. Writing "2500 cm" is ambiguous — a reader can't tell if those zeros count. Write 2.50 × 10³ cm. Scientific notation is the only way to show trailing zeros that are significant.

Same rule, real chemistry

06 The three power-ups

Density, the periodic table, and Avogadro's number are all just conversion factors in disguise. Each one links two quantities, so each one can be written either way up — and you pick the way that cancels what you're holding.

Density as a factor · 30.6 g of a metal, d = 11.3 g/cm³ → find volume
30.6 g× 1.0 cm³11.3 g =2.71 cm³
Molar mass as a factor · moles in 36.6 g of Al  (26.98 g/mol)
36.6 g Al× mol Al26.98 g Al =1.36 mol
All three chained · atoms in 56.3 g of K  (39.10 g/mol) — Workshop problem 25
56.3 g K× mol39.10 g K× 6.02×10²³ atomsmol =8.67 × 10²³ atoms
⚡ Write the element in the unit

Your workshop insists on this, and it matters: write g K and mol K, not just "g" and "mol." Every element has a different molar mass, so "grams of K" and "grams of Fe" are genuinely different units that must not cancel each other.

Cover it with your thumb

07 The Triangle Toolkit

Every relationship in Workshop 1 with three quantities fits in a triangle. Cover the one you want, and the triangle hands you the formula: letters side-by-side = multiply, letters stacked = divide.

Triangle 1 · Any unit conversion
WANT = HAVE × FACTOR  ·  length, mass, volume & prefixes
Wwant Hhave Ffactor ×
cover WW = H × F
cover HH = W ÷ F
cover FF = W ÷ H
Workshop #5: 16.2 cm → in. FACTOR = 1.00 in / 2.54 cm  →  16.2 ÷ 2.54 = 6.38 in.
Triangle 2 · Density
m = d × V  ·  mass, density, volume
mmass g dg/cm³ Vcm³ ×
cover mm = d × V
cover dd = m ÷ V
cover VV = m ÷ d
Workshop #18: m = 15.6 g, d = 10.6 g/cm³. Cover V → 15.6 ÷ 10.6 = 1.47 cm³.
Triangle 3 · Grams ↔ Moles
g = n × M  ·  grams, moles, molar mass (periodic table)
ggrams nmoles Mg/mol ×
cover gg = n × M
cover nn = g ÷ M  (moles!)
cover MM = g ÷ n
Workshop #21: 0.698 mol Co, M = 58.93 g/mol. Cover g → 0.698 × 58.93 = 41.1 g.
Triangle 4 · Moles ↔ Particles
P = n × Nₐ  ·  particles, moles, Avogadro's number (6.02 × 10²³)
Pparticles nmoles Nₐ6.02×10²³ ×
cover PP = n × Nₐ
cover nn = P ÷ Nₐ
cover NₐNₐ = P ÷ n
Workshop #23: 0.250 mol Na. Cover P → 0.250 × (6.02 × 10²³) = 1.51 × 10²³ atoms.
⚡ The decimal trick — make the ×10²³ cancel like a unit

Going atoms → moles means dividing by 6.02 × 10²³, and the powers of ten scare people. They shouldn't. Rewrite your number so it also carries ×10²³ — then the 10²³ on top and bottom cancels exactly like a unit, and you just divide the front numbers.

◀ Move decimal LEFT
exponent goes UP (+1 per hop)
3.05 × 10²⁰ → 0.305 × 10²¹
Move decimal RIGHT ▶
exponent goes DOWN (−1 per hop)
3.05 × 10²⁰ → 30.5 × 10¹⁹

Memory hook: “Left = Larger exponent.”

Why it works: sliding the decimal one place left divides the front number by 10, so the exponent must go up by 1 to keep the value the same. You're not changing the number — only how it's dressed.

Workshop problem 24 — moles in 3.05 × 10²⁰ atoms of He?
n = (3.05 × 10²⁰ atoms) ÷ (6.02 × 10²³ atoms/mol)
Step 1 — match the exponent: move the decimal 3 places LEFT, so 20 → 23
3.05 × 10²⁰ ◀ 3 hops left, +3 = 0.00305 × 10²³
Step 2 — now the 10²³ cancels top & bottom, exactly like a unit
0.00305 × 10²³÷6.02 × 10²³=0.00305 ÷ 6.02
Answer (3 sig figs)
= 5.07 × 10⁻⁴ mol
✓ Triangle vs. tracks — when to use which

The triangle is fast recall for a single three-quantity relationship. The railroad tracks win whenever you chain steps or cross units (g → mol → atoms, or in² → cm²) — a triangle holds only three boxes, but the tracks take as many fractions as you need. Triangle for speed, tracks for everything.

Keep these in your pocket

08 Tricks & memory hooks

1

“To” on top, “from” on the bottom

The one rule. The "from" unit cancels automatically, so you never guess multiply vs. divide.

2

Unit didn't cancel? Flip it.

A wrong leftover unit means the fraction went in upside down. Flip that one factor and run it again.

3

The 1000-staircase

M · k · base · m · mc · n are each ×1000 apart. Only deci and centi break the pattern, and they live between base and milli.

4

Smaller unit = bigger number

Converting to a smaller unit? The count grows. To a bigger unit? It shrinks. Catches flipped factors instantly.

5

Cover it with your thumb

Density, moles, atoms: draw the triangle, cover what you want. Side-by-side = ×, stacked = ÷.

6

“Left = Larger” for exponents

Decimal left raises the power of ten; right lowers it. Use it to match 10²³ so Avogadro's number cancels.

7

Exact factors don't cost sig figs

Prefix conversions (1 kg = 1000 g) are definitions — infinitely precise. Only measured factors (454 g/lb) can limit your answer.

8

Squared once, cubed three times

cm² converts twice, cm³ converts three times — and you square or cube the number, not just the unit.

Cheat sheet

09 Every factor you need

Metric ↔ English — exactly as your workshop table gives them
Physical propertyMetricEnglishConversion factor
Massgram (g)pound (lb)454 g = 1.00 lb
VolumemLfluid ounce29.5 mL = 1.00 fl oz
Lengthcminch (in)2.54 cm = 1.00 in
Volume (exact)cm³mL1 cm³ = 1 mL
Molar masses used in Workshop 1 (g/mol)
AlFeCuCoAuKNaHe
26.9855.8563.5558.93196.9739.1022.994.003
📄 Printable version

A one-page PDF of this entire cheat sheet — factors, the prefix staircase, all four triangles, and the decimal trick — is provided alongside this guide.

All 25 problems, worked

10 Verified answer key

Every practice problem from Workshop 1, with the setup written the way you should write it. Answers use your workshop's own factors (454 g/lb, 29.5 mL/fl oz, 2.54 cm/in) and correct significant figures.

Workshop 1 · complete answer key
#ProblemSetup — "to" on top, "from" on bottomAnswer
Metric ↔ English conversions
136.8 lb → g36.8 lb × (454 g / 1.00 lb)1.67 × 10⁴ g
2956 g → lb956 g × (1.00 lb / 454 g)2.11 lb
3156.0 fl oz → mL156.0 fl oz × (29.5 mL / 1.00 fl oz)4.60 × 10³ mL
4356.0 mL → fl oz356.0 mL × (1.00 fl oz / 29.5 mL)12.1 fl oz
516.2 cm → in16.2 cm × (1.00 in / 2.54 cm)6.38 in
6985 in → cm985 in × (2.54 cm / 1.00 in)2.50 × 10³ cm
71450 g → lb1450 g × (1.00 lb / 454 g)3.19 lb
Metric prefixes — factors are exact, so sig figs come from the measurement
82348 mL → L2348 mL × (1 L / 1000 mL)2.348 L
955.6 cm → m55.6 cm × (1 m / 100 cm)0.556 m
10895 g → kg895 g × (1 kg / 1000 g)0.895 kg
110.000056 g → mcg0.000056 g × (1,000,000 mcg / 1 g)56 mcg
120.0296 L → mL0.0296 L × (1000 mL / 1 L)29.6 mL
Multi-step chains & powered units
1363.5 lb → kg63.5 lb × (454 g / 1.00 lb) × (1 kg / 1000 g)28.8 kg
1432.0 fl oz → L32.0 fl oz × (29.5 mL / 1.00 fl oz) × (1 L / 1000 mL)0.944 L
1526.2 cm³ → mm³26.2 cm³ × (10 mm / 1 cm)³  → ×10002.62 × 10⁴ mm³
16568 mcg → mg568 mcg × (1 g / 10⁶ mcg) × (1000 mg / 1 g)0.568 mg
Density — Triangle 2
17d = 10.6 g/cm³, V = 25 cm³ → mass25 cm³ × (10.6 g / 1 cm³)  ·  cover m → m = d × V265 g
2.7 × 10² g at 2 s.f.
18m = 15.6 g, d = 10.6 g/cm³ → volume15.6 g × (1 cm³ / 10.6 g)  ·  cover V → V = m ÷ d1.47 cm³
Molar mass — Triangle 3
1918.3 g Fe → mol18.3 g Fe × (1 mol Fe / 55.85 g Fe)0.328 mol
2026.9 g Cu → mol26.9 g Cu × (1 mol Cu / 63.55 g Cu)0.423 mol
210.698 mol Co → g0.698 mol Co × (58.93 g Co / 1 mol Co)41.1 g
2225.9 mol Au → g25.9 mol Au × (196.97 g Au / 1 mol Au)5.10 × 10³ g
Avogadro's number — Triangle 4
230.250 mol Na → atoms0.250 mol × (6.02 × 10²³ atoms / 1 mol)1.51 × 10²³ atoms
243.05 × 10²⁰ atoms He → mol3.05 × 10²⁰ atoms × (1 mol / 6.02 × 10²³ atoms)5.07 × 10⁻⁴ mol
2556.3 g K → atoms56.3 g K × (1 mol / 39.10 g K) × (6.02 × 10²³ atoms / 1 mol)8.67 × 10²³ atoms
⚠ Note on problem 17

10.6 × 25 = 265 exactly. If you treat "25 cm³" as two significant figures, the reported answer is 2.7 × 10² g. If your instructor treats 25 as an exact count, 265 g stands. Ask which convention applies — this is the single most common place students and graders disagree.

Lock it in

11 The 5 things you must know

  1. Units are variables — the same unit on top and bottom cancels.
  2. "To" on top, "from" on the bottom — the "from" unit cancels, so you never guess multiply or divide.
  3. The leftover unit is your answer's unit — and your built-in error check.
  4. Three quantities? Use a triangle — cover what you want; conversions, density, moles, and atoms all fit.
  5. Exact factors don't limit sig figs — prefixes are definitions; measured factors like 454 g/lb do limit.
⚡ The one line to remember

"Converting TO goes on top, converting FROM goes on the bottom. The 'from' cancels — whatever's left is your answer."