General Chemistry Lab

🧪 Lab 4: Acids, Bases & Buffers

"Why Does Your Blood Stay at pH 7.4 — Even After Drinking Lemonade?"

Your blood is pH 7.4 right now. It was the same an hour ago. It will be the same after lunch. One chemical system is responsible. Today you meet it.

🎯 What You'll Learn Today

🍋 Acids

An acid is an H⁺ (proton) donor. When dissolved in water, acids release H⁺ ions, creating an excess of H₃O⁺ (hydronium).

Example HCl + H₂O → H₃O⁺ + Cl⁻

🧼 Bases

A base is an H⁺ (proton) acceptor. In water, bases accept H⁺ from water molecules, producing OH⁻ (hydroxide).

Example NH₃ + H₂O ⇌ NH₄⁺ + OH⁻

🔄 Conjugate Pairs

Every acid–base reaction creates a conjugate pair. The acid loses H⁺ → conjugate base. The base gains H⁺ → conjugate acid.

HCl / Cl⁻ — conjugate pair
NH₃ / NH₄⁺ — conjugate pair

🛡️ Buffers

A buffer is a mixture of a weak acid and its conjugate base. It resists pH changes when small amounts of acid or base are added.

Your blood is buffered at pH 7.4 — even after a glass of orange juice (pH 3.5)!

📐 The pH Equation

Definition of pH pH = −log [H⁺]

Acidic (pH < 7)

Higher concentration of H⁺ ions.
Example: 0.1 M HCl → [H⁺] = 0.1 M → pH = 1

Neutral (pH = 7)

[H⁺] = [OH⁻] = 1.0 × 10⁻⁷ M
Pure water at 25°C.

Basic (pH > 7)

Higher concentration of OH⁻ ions.
Example: 0.1 M NaOH → pOH = 1 → pH = 13

The Water Relationship [H⁺] × [OH⁻] = 1.0 × 10⁻¹⁴   →   pH + pOH = 14
⚠️ The Log Trap: Each pH unit = a 10× change in H⁺ concentration. pH 3 is not "a little more acidic" than pH 5 — it's 100 times more acidic. Lemon juice (pH 2) vs. your blood (pH 7.4) is a 2,500,000× difference in H⁺ concentration. Your stomach wall survives pH 1.5 every day. That same acid dissolves a tooth in hours.

🎮 Interactive: Match the Conjugate Pairs

Click an acid, then click its conjugate base. Match all 5 pairs!

Pairs matched: 0 / 5

🌈 Interactive pH Scale Explorer

Hover over or click any pH value to explore common substances and their acidity/basicity.

7
Pure Water
Neutral — [H⁺] = [OH⁻] = 1.0 × 10⁻⁷ M

🧪 Lab Solutions at a Glance

These are the 10 solutions you'll test in Part 1. Colors approximate the pH indicator reading.

⚡ Strong vs Weak: The Big Difference

Strong Acids & Bases

Dissociate 100% in water. Every molecule breaks apart.

HCl → H⁺ + Cl⁻  (complete)

For strong acids: [H⁺] = [acid]
For strong bases: [OH⁻] = [base]

Strong AcidsStrong Bases
HCl — hydrochloric acidNaOH — sodium hydroxide
HBr — hydrobromic acidLiOH — lithium hydroxide
HI — hydroiodic acidKOH — potassium hydroxide
H₂SO₄ — sulfuric acidBa(OH)₂ — barium hydroxide
HNO₃ — nitric acid
HClO₄ — perchloric acid

Weak Acids & Bases

Only partially dissociate — an equilibrium exists between the undissociated molecule and its ions.

CH₃COOH ⇌ CH₃COO⁻ + H⁺  (partial)

For weak acids: [H⁺] ≪ [acid]
Most acid molecules stay intact!

Key insight: 0.1 M HCl has pH ≈ 1, but 0.1 M acetic acid has pH ≈ 2.9. Same concentration, very different pH — because acetic acid barely dissociates!

🔬 Dissociation Visualizer

See the difference between strong and weak acid dissociation:

Click a button above to visualize dissociation

🔄 What Happens to Conjugate Partners?

Conjugate Base of a Weak Acid acts as a Base

Acetic acid (CH₃COOH) is weak, so its conjugate base CH₃COO⁻ (acetate) is strong enough to accept an H⁺ from water:

CH₃COO⁻ + H₂O ⇌ CH₃COOH + OH⁻

This is why sodium acetate solution is basic (pH > 7).

Conjugate Acid of a Weak Base acts as an Acid

Ammonia (NH₃) is a weak base, so its conjugate acid NH₄⁺ (ammonium) donates H⁺ to water:

NH₄⁺ + H₂O ⇌ NH₃ + H₃O⁺

This is why ammonium chloride solution is acidic (pH < 7).

Rule of thumb: The conjugate of a strong acid/base is so stable it doesn't react with water (spectator). The conjugate of a weak acid/base is reactive enough to shift the pH.

🛡️ What Is a Buffer?

A buffer is a solution that resists changes in pH when small amounts of acid or base are added. It consists of:

Weak Acid + Conjugate Base

Acetate buffer: CH₃COOH + CH₃COO⁻ (from sodium acetate)

• Weak acid neutralizes added base
• Conjugate base neutralizes added acid

Weak Base + Conjugate Acid

Ammonia buffer: NH₃ + NH₄⁺ (from ammonium chloride)

• Weak base neutralizes added acid
• Conjugate acid neutralizes added base

🩸 Your blood, right now: pH 7.4. Orange juice is pH 3.5 — 10,000× more acidic. A shot of espresso is pH 5. None of it moves your blood pH by more than 0.05 units. The carbonate buffer (H₂CO₃ / HCO₃⁻) absorbs every proton before it reaches your arteries. Drop to pH 7.1 and the heart starts arrhythmia. Drop to pH 6.8 and seizures begin. The window is 0.1 units wide. The buffer holds it there every second you're alive.

How a Buffer Works — Step by Step

1

Acid is added → Conjugate base absorbs it

Added H⁺ reacts with the conjugate base (CH₃COO⁻), converting it back to weak acid. The H⁺ is consumed, so pH barely changes.

CH₃COO⁻ + H⁺ → CH₃COOH
2

Base is added → Weak acid absorbs it

Added OH⁻ reacts with the weak acid (CH₃COOH), converting it to conjugate base + water. The OH⁻ is consumed, so pH barely changes.

CH₃COOH + OH⁻ → CH₃COO⁻ + H₂O

🎛️ Interactive Buffer Simulator

Choose a solution, then add acid or base to see how pH responds. Compare buffered vs unbuffered!

Initial pH
7.00
Final pH (after additions)
7.00
ΔpH = 0.00 — No change yet. Try adding some drops!

🩺 Clinical Corner: When the Buffer Fails

The carbonate buffer keeps blood pH in a 0.1-unit window. Outside that window, organs stop working in a specific, predictable order.

Blood pHConditionWhat the Body DoesIf Untreated
> 7.8 Severe Alkalosis Muscle tetany, seizures Cardiac arrest
7.45–7.8 Alkalosis Muscle cramps, tingling, confusion Worsening neurological symptoms
7.35–7.45 ✅ Normal All systems functioning
7.0–7.35 Acidosis Rapid breathing (exhaling CO₂ to compensate), confusion, fatigue Organ failure
< 7.0 Severe Acidosis Cardiac arrhythmia, coma Death within hours
The specific number: pH 7.4 to pH 7.1 is a drop of 0.3 units. On the logarithmic scale, that's a 100% increase in [H⁺] — a doubling of acid concentration in the blood. That's the difference between healthy and a cardiac emergency. The buffer holds it at 0.3 units every second. It never rests.

📊 Why Water Has No Defense

Compare what happens when you add 5 drops of HCl to each solution:

SolutionInitial pHAfter 5 drops HClΔpHVerdict
Distilled Water 7.00 ~3.0 −4.0 ⚠️ Huge swing!
Acetate Buffer ~4.74 ~4.56 −0.18 ✅ Barely moved
Ammonia Buffer ~9.25 ~9.07 −0.18 ✅ Barely moved
The difference: Water has nothing. No reserve, no system. The H⁺ arrives and pH plummets. The buffer has a waiting supply of CH₃COO⁻ — each molecule a trap for exactly one incoming H⁺, converting it to harmless CH₃COOH instead. The H⁺ disappears. The pH holds.

⚠️ Safety First

Required: Safety goggles must be worn at all times.
Caution: 0.1 M HCl and 0.1 M NaOH are dilute but can still irritate skin and eyes. Rinse immediately with water if contact occurs. Notify your instructor.

🔬 Part 1: pH of Everyday Chemicals

You'll measure the pH of 10 solutions using pH paper (test strips).

1

Prepare 10 test tubes

Place them in a test tube rack. Pour about 3 mL of each solution into its own test tube.

2

Test with pH paper

Dip a clean glass rod into the solution. Touch the rod to the pH test strip. Use a fresh strip for each solution!

3

Read and Record

Compare the color on the strip to the chart on the pH paper box. Record the pH and classify as acidic, basic, or neutral.

Solutions to test: Bleach, Vinegar, Lemon Juice, Distilled Water, 0.1 M HCl, 0.1 M NaOH, 0.1 M Acetic Acid (CH₃COOH), 0.1 M Sodium Acetate (CH₃COONa), 0.1 M Ammonia (NH₄OH), 0.1 M Ammonium Chloride (NH₄Cl)

🔬 Part 2: Effect of Buffers on pH

You'll compare how water, an acetate buffer, and an ammonia buffer respond to added acid and base.

1

Set up 6 test tubes

Tubes 1 & 2: Add 10 mL distilled water to each.
Tubes 3 & 4: Add 5 mL of 0.1 M CH₃COOH + 5 mL of 0.1 M CH₃COONa to each (acetate buffer).
Tubes 5 & 6: Add 5 mL of 0.1 M NH₄OH + 5 mL of 0.1 M NH₄Cl to each (ammonia buffer).

2

Measure initial pH

Use the pH meter to record the pH of all 6 test tubes. Rinse the probe with RO water between measurements!

3

Add acid to odd-numbered tubes

Add 5 drops of 0.1 M HCl to tubes 1, 3, and 5. Mix well. Measure and record the new pH.

4

Add base to even-numbered tubes

Add 5 drops of 0.1 M NaOH to tubes 2, 4, and 6. Mix well. Measure and record the new pH.

💡 What to watch for: Compare the ΔpH for water vs the buffers. The buffer solutions should show dramatically smaller pH changes — that's the buffer in action!

📋 Part 1 Data: pH of Everyday Chemicals

Solution pH Classification Strong/Weak/N/A

📋 Part 2 Data: Buffer Effect

Test Tube Solution Initial pH Addition Final pH ΔpH
1Distilled Water 5 drops HCl
2Distilled Water 5 drops NaOH
3Acetate Buffer 5 drops HCl
4Acetate Buffer 5 drops NaOH
5Ammonia Buffer 5 drops HCl
6Ammonia Buffer 5 drops NaOH

🧮 pH / pOH Calculator

Enter any ONE value — the rest will be calculated:

⚖️ Henderson-Hasselbalch Buffer Calculator

Henderson-Hasselbalch Equation pH = pKₐ + log([A⁻] / [HA])
[A⁻] = conjugate base concentration  |  [HA] = weak acid concentration  |  When [A⁻] = [HA], log(1) = 0, so pH = pKₐ — the buffer's optimal point.
pH = 4.74 + log(1.00) = 4.74 + 0.00 = 4.74
Equal concentrations → pH = pKₐ. This is the buffer's sweet spot — maximum resistance to both acid and base addition.

🔄 Quick Conversions

[H⁺] (M)pHpOH[OH⁻] (M)Acidic/Basic?
1.0 × 10⁻¹1.013.01.0 × 10⁻¹³Strongly Acidic
1.0 × 10⁻³3.011.01.0 × 10⁻¹¹Acidic
1.0 × 10⁻⁵5.09.01.0 × 10⁻⁹Weakly Acidic
1.0 × 10⁻⁷7.07.01.0 × 10⁻⁷Neutral
1.0 × 10⁻⁹9.05.01.0 × 10⁻⁵Weakly Basic
1.0 × 10⁻¹¹11.03.01.0 × 10⁻³Basic
1.0 × 10⁻¹³13.01.01.0 × 10⁻¹Strongly Basic

✅ Self-Check Quiz

Test your understanding before, during, or after the lab. Click an answer to check it — explanations included!

0 / 15